Notepad++ (npp) is a friendly, free and open source Windows Notepad replacement and code editor that supports syntax highlighting in a multitude of languages. Custom languages can be defined and all kinds of plugins are available, such as file explorers, file comparing tools, clipboard managers, and a lot more.
Once upon a time, there was a highly useful ColorPicker plugin, allowing modification and creation of source code color values, e.g. HTML hex colors, directly inside the editor. However, with the conversion of Notepad++ to Unicode, the plugin stopped working and it never received an update.
[ Update March 24, 2013: The original ColorPicker has received and is now available for Unicode, as well. ]
Pixabay staff member Simon developed a new version of the plugin, which is freely available - both as source code and compiled binaries - right here and on SourceForge.
The plugin supports color values in HTML (hex #RGB), Delphi (integer and hex $00BGR), Visual Basic (&BGR), C++ (0x00BGR), and byte RGB (R,G,B).
Download
ColorPicker Plugin (Binaries/DLL, zip file, 230 kb)
ColorPicker Source Code (Delphi project, 7z file, 30 kb)
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I tend to agree with you about web-safe colors. However, some coders still prefer web safe colors. HTML validators may still flag non-web-safe colors as a hint or warning. The conversion algorithm is short and easy to follow so implementation is easy.